Product ID:CCA TREATED WOOD AND LUMBER, 00000052
MSDS Date:06/01/1991
FSC:5510
NIIN:00N039273
MSDS Number: BRKZH

KOP-COAT INC

436 SEVENTH AVE
PITTSBURGH, PA 15219-1800
US

Emergency Phone: 800-553-5631;800-424-9300(CHEMTREC)

Info Phone: 412-227-2884

Preparer: OCCUP HLTH/PROD SFTY DEPT

Cage: 00297

KOP-COAT INC

PITTSBURGH, PA 15219-1818 US

Telephone: 800-553-5631, CHEMTREC 800-424-9300

Cage: 00297

CLOTHING CHANGE RECOMMENDED AT THE END OF EACH SHIFT.

RTECS: 9999999ZZ

OR INDUSTRIAL USE (E.G., CONSTRUCTION

RTECS: 9999999ZZ

INCINERATORS OR BOILERS I/A/W STATE AND FEDERAL

RTECS: 9999999ZZ

STATE AND FEDERAL REGULATIONS .

RTECS: 9999999ZZ

CHRONIC OBSTRUCTIVE LUNG CHANGES/NASAL

RTECS: 9999999ZZ

FROM EXPOS TO HARDWOOD DUST. THE EFTS OF INDUSTRIAL

RTECS: 9999999ZZ

CCA WOOD HAS BEEN EVALUATED IN THREE INDEPENDENT

RTECS: 9999999ZZ

WORKERS EXPOSED ON A DAILY BASES TO THESE

RTECS: 9999999ZZ

CHROMIUM (SARA III)

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: <5%

OSHA PEL 1 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ARSENIC (SARA III)

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: <5% PPM

OSHA PEL 0.5 MG/M3 (AS)

ACGIH TLV: 0.01,A1 MG/M3; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

COPPER (SARA III)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: <5%

OSHA PEL 0.1MG/M3 FUME;1 DUST

ACGIH TLV: 0.2MG/M3 FUME;1 DUST

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WOOD; (CERTAIN HARD WOODS SUCH AS BEECH & OAK), (SOFTWOOD))

Fraction By Weight: >85%

OSHA PEL 5 MG/M3;10 STEL

ACGIH TLV: 5MG/M3;10 STEL

VOMIT OR GIVE 1-2 OZ (30-60 G) ACTIVATED CHARCOAL

RTECS: 9999999ZZ

FROM OTHER HOUSEHOLD CLOTHING.

RTECS: 9999999ZZ

BELOW EXPLOSIVE DUST CONCENTRATIONS.

RTECS: 9999999ZZ

WORKING W/PROD & BEFORE EATING/DRINKING,

RTECS: 9999999ZZ

W/OUT PROPER EYE PROT WHEN USING PROD. THIS PROD MUST

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE:TREATED OR UNTREATED WOOD DUST MAY
CAUSE MECHANICAL IRRITATION. SKIN:PROLONGED AND/OR REPEATED DIRECT
CONTACT WITH TREATED OR UNTREATED WOOD DUST MAY CAUSE MILD,
TRANSIENT IRRITATION. INHAL:FINELY DIVIDED TREATED OR UNTREATED
WOOD DUSTMAY CAUSE NOSE, THROAT OR LUNG IRRIT & OTHER RESP EFTS.
(EFTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:ARSENIC:KNOWN CARCINOGEN(NTP 6'TH ANN
RPT,'91)IARC GRP 1 (VOL.7,P.100,'87)OSHA REGULATED 1910.1018..
Effects of Overexposure:HLTH HAZ:INGEST:A SINGLE INGEST BY SMALL CHILD
OF APPROX 2.5 OZ (6 CUBIC INCHES) OF TREATED WOOD DUST MAY BE LIFE
THREATENING. THE PRINCIPAL HLTH EFTS REPORTED FROM OCCUP EXPOS TO
SAWDUST OR WOOD DUST GENERATED FROM UNTREATED WOOD ARE DERM,
RHINITIS, CONJUNCT, REDUCED OR SUPRESSED MUCOCILIARY CLEARANCE
RATES, (ING 14)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASE OR A HISTORY OF AILMENTS INVOLVING SKIN, KIDNEY, LIVER,
RESPIRATORY TRACT, EYES OR NERVOUS SYSTEM ARE AT GREATER NORMAL
RISK OF DEVELOPING ADVERSE EFFECTS.

First Aid:EYE:GENTLY FLUSH ANY PARTICLES WITH LARGE AMTS OF COLD WATER
FOR AT LEAST 15 MINS. DO NOT RUB EYES. SKIN:RINSE SKIN FREE OF MATL
W/WATER TO AVOID ABRASION OF SKIN. DO NOT RUB UNTIL SKIN IS FREE OF
MAT L THEN WASH THORO W/SOAP & WATER. INHAL:REMOVE FROM EXPOS. IF
BRTHG HAS STOPPED OR IS DFCLT, GIVE ARTF OR O*2 AS INDICATED. GET
MD. INGEST:IF 2 OUNCES OR GREATER ARE EATEN, SEE NOTE TO MD.
(SUPDAT)

Extinguishing Media:USE WATER STREAM/SPRAY/FOG. USE METHODS APPLICABLE
TO SURROUNDING AREA.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . USE WATER TO COOL FIRE-EXPOSED
CONTAINER/STRUCTURE/PROTECT PERSONNEL.
Unusual Fire/Explosion Hazard:DUST MAY FORM EXPLOSIVE MIXTURE IN AIR.
UNDER FIRE CONDITIONS, MAY EMIT IRRITANT/TOXIC GAS AND/OR FUMES.

Spill Release Procedures:NOT APPLICABLE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID FREQUENT OR PROLONGED CONTACT
W/SKIN OR INHAL OF TREATED WOOD DUSTS. WHEN SAWING/MACHINING
TREATED WOOD, WEAR DUST MASK.
Other Precautions:WHENEVER POSS, SAWING/MACHINING TREATED WOOD SHOULD
BE PERFORMED OUTDOORS TO AVOID ACCUMULATIONS OF AIRBORNE TREATED
WOOD SAWDUST. IF PRESERVATIVES/SAWDUST ACCUMULATE ON CLOTHES,
LAUNDER BEFORE REUSE. WASH WORK CLOTHES SEPARATELY (ING 6)

Respiratory Protection:NOT REQUIRED UNDER NORMAL USE CONDITIONS. WHEN
SAWING OR MACHINING TREATED WOOD, WEAR A NIOSH/MSHA APPROVED DUST
MASK (TC-21C).
Ventilation:PROVIDE SUFFICIENT GEN/LOCAL EXHST VENT IN PATTERN/VOLUME
TO CNTRL INHAL (MOLTEN) EXPOS BELOW CURRENT EXPOS/AREAS(ING 7)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:IND SFTY GLASS & SIDE SHIELDS,GOG(SUPDA)
Other Protective Equipment:PROTECTIVE APPAREL TO INCLUDE HEAD, HAND &
SAFETY-TYPE FOOTWEAR.
Work Hygienic Practices:OBSERVE GOOD HYGIENE & SAFETY PRACTICES WHEN
HANDLING PROD. WASH EXPOSED AREAS THORO AFTER SKIN CNTCT FROM (ING
8)
Supplemental Safety and Health
EYE PROT:OR FSHLD.HAZ DECOMP PROD:CHROME & ARSENIC.THE METALS MAY
REMAIN IN WOOD ASH AS WELL AS BE RELS IN AIR.FIRST AID PROC:NOTE TO
MD:IF ONE OZ OF TREATED WOOD DUST PER 10 LBS OF BODY WEIGHT ARE IN
GEST,ACUTE ARSENIC INTOX IS A POSS.INGEST:GIVE 1-2 GLASSES OF MILK
OR WATER TO VICTIM IF CONSCIOUS & ALERT.INDUCE(ING 5)

Spec Gravity:SAME AS WOOD
Solubility in Water:HIGHLY SOLUBLE
Appearance and Odor:TREATMENT IMPARTS A LIGHT GREEN COLOR TO THE WOOD
Corrosion Rate:YN/KOWN

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OPEN FLAME.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CNTCT W/STRONG ACID MAY LIBERATE
PRESERVATIVE METALS. COMBUST PRODS INCL CARBON MONOXIDE, OXIDES OF
NITROGEN,(SUPP DATA)

Waste Disposal Methods:DISPOSE OF TREATED WOOD BY ORDINARY TRASH
COLLECTION/BURIAL. TREATED WOOD SHOULD NOT BE BURNED IN OPEN FIRES
OR STOVES, FIREPLACES OR RESIDENTIAL BOILERS BECAUSE TOX CHEMS MAY
BE PRODUCED AS PART OF SMOKE/ASHES. TREATED WOOD FROM COMMERCIAL
(ING 11)

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